Knowing that an application uses MAPI does not allow you to predict what protocol will be used to communicate between a client and a server. Instead, you need to know what protocols the MAPI driver is using; usually the easiest way to determine this is to determine what kind of server is being used. Probably the biggest user of MAPI is the Microsoft Exchange client, which is provided with MAPI drivers that use Microsoft RPC to speak to Microsoft Exchange servers.
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